Zirconium Hafnium Separations

Separation of zirconium and hafnium from nitric acid ...

The stripping of zirconium and hafnium from loaded LIX 63 containing 0.137 g/L of Zr and 0.02 g/L of Hf was carried out by varying the concentration of H 2 SO 4 and HCl solutions. The effect of the stripping agent concentration on the stripping percentage of zirconium and hafnium is shown in Fig. 11 .

Separation of zirconium and hafnium using Diphonix ...

The sorption behavior and possible separation of zirconium and hafnium from acid solution was studied on Diphonix® chelating resin containing diphosphonic, sulfonic and carboxylic acid groups.

Zirconium and hafnium separation without waste generation

The history of commercial processes for zirconium/hafnium production and separation is reviewed. A new technology is then proposed as a potential alternative for zirconium/hafnium separation in a ...

Zirconium and Hafnium Separation, Part 2. Solid/Liquid ...

Zirconium and Hafnium Separation, Part 2. Solid/Liquid Extraction in Hydrochloric Acid Aqueous Solution with Anion Exchange Resins

separation hafnium process - hanvanlamoen.nl

Hafnium: Hafnium (Hf), stone element (atomic number 72), metal of . distillation as the preferred methods of separating hafnium from zirconium. . The metal itself is prepared by magnesium reduction of hafnium tetrachloride (Kroll process,.

Application of liquid-liquid extraction for the separation ...

Application of liquid-liquid extraction for the separation of zirconium from hafnium Abstract The use of liquid-liquid extraction for the separation of zirconium from hafnium was demonstrated.

v116n1a14 Solvent extraction and separation of hafnium ...

Solvent extraction and separation of hafnium from zirconium using Ionquest 801 94 VOLUME 116 Consequently, concentrations of impurities relative to Zr as

Zirconium-hafnium separation and purification process ...

03/11/1992 · Zirconium and hafnium tetrachloride vapors were condensed in two barn condensers, equipped with external cooling-water jackets. The remaining off-gases, containing primarily chlorine, carbon monoxide, carbon dioxide, phosgene, silicon tetrachloride, and nitrogen purge gas, were treated in a caustic scrubber. Samples of off-gas were also collected and analyzed by gas chromatography.

Hafnium/Zirconium Separation Using Cyanex 925

C ANADIAN M ETALLURGICAL Q UARTERLY HAFNIUM/ZIRCONIUM SEPARATION USING CYANEX 925 A. DASILVA, E. EL-AMMOURI and P.A. DISTIN Department of …

US5618502A - Zirconium and hafnium separation in sulfate ...

A method and system for improved continuous ion exchange chromatographic elemental separations of zirconium and hafnium and also for isotopic separations thereof from crude zirconium minerals by using zirconium (also containing hafnium) sulfate feedstock solutions, sulfate eluant solutions, anionic exchange resins, and reduced ion exchange ...

WO1997003743A1 - Zirconium and hafnium separation in ...

A method and system for improved continuous ion exchange chromatographic elemental separations of zirconium and hafnium and also for isotopic separations thereof from crude zirconium minerals by using zirconium (also containing hafnium) sulfate feedstock solutions, sulfate eluant solutions, anionic exchange resins, and reduced ion exchange ...

Uranium-preextraction in zirconium/hafnium separations ...

03/04/1990 · Uranium-preextraction in zirconium/hafnium separations process ... ore in which uranium chloride is volatilized at the ore chlorinator temperature and follows as an impurity in the zirconium-hafnium tetrachloride stream, and in which removal of iron impurities is performed by liquid-liquid iron extraction with methyl isobutyl ketone, and the zirconium-hafnium stream is further …

1 Zirconium and Hafnium - Home - Springer

1 Zirconium and Hafnium The three pairs of metals Y, Lu; Zr, Hf; Nb, Ta show a striking resemblance bet­ ween the lighter and the heavier metal of each pair, arising from the predominant

The separation of zirconium and hafnium by distillation ...

zirconium tetrachloride contained an approximate ratio of 3/100 hafnium tetrachloride, ~y weigbt, with lesser amounts of iron, titanium, aluminum, and chromium.

Analytical Chemistry of Zirconium and Hafnium - 1st Edition

Analytical Chemistry of Zirconium and Hafnium compiles literature on the characterization and analysis of zirconium and hafnium. Various methods in studying the properties of the featured elements are presented in this book.

Zirconium and Hafnium in Stone Meteorites | Science

Abstract. The abundances of zirconium and hafnium in stone meteorites, were determined by neutron activation analysis. Specific radiochemical separations were used to obtain individual zirconium and hafnium samples of high radiochemical purity.

Extraction and separation of zirconium from hafnium using ...

Abstract. A simple method based on the dispersive liquid–liquid microextraction and a solidification of floating organic drop followed by an inductively coupled plasma-optical emission spectrometry (ICP-OES) was developed for the extraction and separation of zirconium from hafnium.

Energies - MDPI - Publisher of Open Access Journals

This study examined the environmentally benign separation of zirconium tetrachloride (ZrCl 4) and hafnium tetrachloride (HfCl 4) for nuclear power reactor applications through extractive distillation using a NaCl-KCl molten salt mixture.

Energies | Free Full-Text | Design of an Extractive ...

This study examined the environmentally benign separation of zirconium tetrachloride (ZrCl 4) and hafnium tetrachloride (HfCl 4) for nuclear power reactor applications through extractive distillation using a NaCl-KCl molten salt mixture.

Continuous ion exchange separation of zirconium and hafnium

A pressurized continuous annular chromatograph (CAC) has been developed for truly continuous ion exchange preparative separations. This device utilizes a slowly rotating annular bed of sorbent material, fixed multiple feed points, and fixed withdrawal locations.

Continuous ion exchange separation of zirconium and hafnium

A pressurized continuous annular chromatograph (CAC) has been developed for truly continuous ion exchange preparative separations. This device utilizes a slowly rotating annular bed of sorbent material, fixed multiple feed points, and fixed withdrawal locations.

Separate and simultaneous determination of zirconium and ...

The use of xylenol orange as a spectrophotometric reagent for zirconium and hafnium has been investigated for their determination in the range 0·002 to 0·2 per cent. in complex nickel-base alloys, and the effects of major alloying elements, and likely impurities, have been studied.

Separation of Hafnium and Zirconium from Ti- and Fe-Rich ...

This stone presents a new stone separation method for Hf and Zr from rocks using extraction chromatographic resins prepared from inert polymeric supports and the liquid anionic exchangers tri-n-octylamine or trioctylmethylammonium chloride (Aliquat 336).

Full text of "Review of anhydrous zirconium-hafnium ...

Full text of "Review of anhydrous zirconium-hafnium separation techniques" See other formats No 8963 ^.-'^'^ <. o V »- o.

The separation of some inorganic compounds by liquid ...

THE SEPARATION OF SOME INORGANIC COMPOUNDS BY LIQUID-LIQUID EXTRACTION by Raymond A» Poos A Dissertation Submitted to the Graduate Faculty in Partial Fulfillment of

Separation of zirconium and hafnium from nitric ... - DeepDyve

Read "Separation of zirconium and hafnium from nitric acid solutions with LIX 63, PC 88A and their mixture by solvent extraction, Hydrometallurgy" on DeepDyve, the largest online rental service for scholarly research with thousands of academic publications available at your fingertips.

RADIOCHEMICAL SEPARATION OF ZIRCONIUM AND HAFNIUM …

The U.S. Department of Energy's Office of Scientific and Technical Information

A RADIOCHEMICAL SEPARATION FOR THE ... - osti.gov

osti.gov journal article: a radiochemical separation for the determination of zirconium or hafnium in rocks and minerals by neutron activation analysis.

Zirconium and hafnium separation in sulfate solutions ...

(54) Title: ZIRCONIUM AND HAFNIUM SEPARATION IN SULFATE SOLUTIONS USING CONTINUOUS ION EXCHANGE CHROMATOGRAPHY Zr PEAK Hf PEAK TIME (OR BED VOLUMES) FOR ELUTION (57) Abstract A method and system for improved continuous ion exchange chromatographic elemental separations of zirconium and hafnium and also for isotopic separations thereof from crude zirconium minerals by using zirconium …

Bubble point measurement and high pressure distillation ...

for the environmentally benign separation of zirconium from hafnium for nuclear power reactor Le Quang Minh * , Gyeongmin Kim * , Jongki Park ** , and Moonyong Lee * ,†